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1 article(s) from Mohadjerani, Maryam

Amidofluorene-appended lower rim 1,3-diconjugate of calix[4]arene: synthesis, characterization and highly selective sensor for Cu²⁺

Rahman Hosseinzadeh,
Mohammad Nemati,
Reza Zadmard and
Maryam Mohadjerani

Beilstein J. Org. Chem. 2016, 12, 1749–1757, doi:10.3762/bjoc.12.163

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Graphical Abstract

Scheme 1: Fluorene appended 1,3-diconjugate of calix[4]arene.

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Scheme 2: Synthesis route of fluorene-appended amido-linked 1,3-diconjugate of calix[4]arene L.

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Figure 1: Absorption spectra of L (1.0 × 10⁻⁵ M) and its complexes with different metals (10 equiv) in MeCN.

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Figure 2: Color changes of receptor L upon addition of 10 equiv of various metal ions as their perchlorate sa...

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Figure 3: Influence of the addition of increasing amounts (0–100 equiv) of Cu²⁺ on the absorption spectra of L...

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Figure 4: Fluorescence spectra of L (1.0 × 10⁻⁵ M) in MeCN upon addition of different metal ions (10 equiv) w...

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Figure 5: (a) Fluorescence spectra (1.0 × 10⁻⁵ M) of L recorded upon the addition of copper ion (0–5 equiv) i...

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Figure 6: Fluorescence intensity of L (1.0 × 10⁻⁵ M) upon the addition of 10 equiv Cu²⁺ in the presence of 10...

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Figure 7: ¹ H NMR (400 MHz, CD₃CN) spectra of L upon addition of (a) 0.0 equiv, (b) 0.2 equiv, (c) 0.4 equiv,...

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Scheme 3: A proposed binding mode between L and Cu²⁺.

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Published 04 Aug 2016

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Amidofluorene-appended lower rim 1,3-diconjugate of calix[4]arene: synthesis, characterization and highly selective sensor for Cu2+

Amidofluorene-appended lower rim 1,3-diconjugate of calix[4]arene: synthesis, characterization and highly selective sensor for Cu²⁺